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Multilayered artifacts in the pre-Columbian metallurgy from the North of Peru Multilayered artifacts in the pre-Columbian metallurgy from the North of Peru

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Fecha
2013
Autores
Cesareo, R
Bustamante, AD
Fabian, JS
Zambrano, SD
Alva, W
Chero, LZ
Espinoza, MCD
Rodriguez, RR
Seclen, MF
Gutierrez, FV
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Springer Heidelberg
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Abstracto
Three types of alloys were recognized when analyzing pre-Columbian artifacts from the North of Peru: gold, silver, and copper alloys; gilded copper and silver; silvered copper; tumbaga, i.e., copper or silver enriched on gold at the surface by depletion gilding. In this paper, a method is described to differentiate gold alloys from gilded copper and from copper-gold tumbaga, and silver alloys from silvered copper and copper-silver tumbaga. This method is based on the use of energy-dispersive X-ray fluorescence, i.e., on a sophisticated analysis of XRF-spectra carrying out an accurate determination of Cu(K α /K β ), Ag(K α /K β ), Au(L α /L β ), and Au-L α /Cu-K α or Ag-K α /Cu-K α ratios. That implies a dedicated software for the quantitative determination of the area of X-ray peaks. This method was first checked by a relevant number of standard samples and then it was applied to pre-Columbian alloys from the North of Peru. © 2013 Springer-Verlag Berlin Heidelberg.
Descripción
This work was partially supported by a bilateral project between the Consiglio Nazionale delle Ricerche and Consejo Nacional de Ciencia, Tecnologia e Innovacion Tecnologica of Peru (CNR-CONCYTEC, 2009-2011 and 2012-2014). F. Lopes acknowledges CAPES for a 7 months grant at the University of Sassari.
Palabras clave
Copper, Gold, Plating, Silver
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