Publicación:
XRF elemental analysis of inks in South American manuscripts from 1779 to 1825

dc.contributor.author Luízar Obregón, Celina es_PE
dc.contributor.author Zamalloa Jara, Marco A. es_PE
dc.contributor.author Rojas Arizapana, Flor L. es_PE
dc.contributor.author Chura Huayllani, Yuri J. es_PE
dc.contributor.author Gonzales Bellido, Janet F. es_PE
dc.contributor.author Olivera Olivera, Jorge es_PE
dc.date.accessioned 2024-05-30T23:13:38Z
dc.date.available 2024-05-30T23:13:38Z
dc.date.issued 2021-11
dc.description This work was carried out with resources from the gas canon of the Cusco Region and the support of FONDECYT—CIENCIACTIVA- CONCYTEC (Res. Dir. 016–2018-FONDECYT-DE; No Reg. 56747). / Producto elaborado en el marco del Proyecto de investigación dentro del Programa YACHAYNINCHIS WIÑARINANPAQ de la UNSAAC y CONCYTEC (FONDECYT/PROCIENCIA).
dc.description.abstract The Regional Archive of Cusco in Peru guards valuable history collections with exceptional regional and international value dating from the sixteenth century to the present. Historical manuscripts are part of the identity of all people; they constitute a tangible cultural heritage that must be studied, valued, and protected. In this sense, the objective of this research was to identify the chemical compositions of inks and paper, with the goals of setting the background of their originality, identifying relationships between them, and glimpsing antecedents that generated degradation due to the compositions of the inks. This study is the first of its kind in Peru and reveals the chemical elements present in the writing ink, the seal, and the paper of five documents from the late eighteenth and early nineteenth centuries. Duplicate in situ nondestructive analyses were carried out using a hand-held X-ray fluorescence spectrometer under ambient conditions in soil mode, configured with three sequential shots, and energies from zero to 40, 40, and 15 keV, respectively. The elements S and Fe were present as components of iron gall inks. Cu and Zn were less abundant; probably, they provided less corrosion and more color intensity to the inks. The minor elements Pb, As, and especially Ag in all manuscripts differentiate them from European inks of the same period. Additionally, the five documents reflect the same elemental compositions but with different concentrations. This could mean that writers used local raw materials and Spanish ink recipes. Finally, the analyses of standard reference material, SRM 1646a and SRM 196b, gave results with acceptable precision.
dc.description.sponsorship Consejo Nacional de Ciencia, Tecnología e Innovación Tecnológica - Concytec
dc.identifier.doi https://doi.org/10.1186/s40494-021-00619-9
dc.identifier.scopus 2-s2.0-85118708099
dc.identifier.uri https://hdl.handle.net/20.500.12390/3215
dc.language.iso eng
dc.publisher Springer Nature
dc.relation.ispartof Heritage Science
dc.rights info:eu-repo/semantics/openAccess
dc.rights.uri https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject Nondestructive characterization
dc.subject Elemental analysis es_PE
dc.subject Iron gall ink es_PE
dc.subject.ocde http://purl.org/pe-repo/ocde/ford#1.05.04
dc.title XRF elemental analysis of inks in South American manuscripts from 1779 to 1825
dc.type info:eu-repo/semantics/article
dspace.entity.type Publication
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