Publicación:
New Insights into Re-3(mu-Cl)(3)Cl-6 Aromaticity. Evidence of sigma- and pi-Diatropicity
New Insights into Re-3(mu-Cl)(3)Cl-6 Aromaticity. Evidence of sigma- and pi-Diatropicity
| dc.contributor.author | Vasquez-Espinal, A | es_PE |
| dc.contributor.author | Pino-Rios, R | es_PE |
| dc.contributor.author | Alvarez-Thon, L | es_PE |
| dc.contributor.author | Rabana-Leon, WA | es_PE |
| dc.contributor.author | Torres-Vega, JJ | es_PE |
| dc.contributor.author | Arratia-Perez, R | es_PE |
| dc.contributor.author | Tiznado, W | es_PE |
| dc.date.accessioned | 2024-05-30T23:13:38Z | |
| dc.date.available | 2024-05-30T23:13:38Z | |
| dc.date.issued | 2015 | |
| dc.description.abstract | It evaluated the behavior of the Re3(μ-Cl)3Cl6 cluster under magnetic perturbation, and it clearly shows that the magnetic response within the Re3(μ-Cl)3 plane is highly diatropic in nature. An analysis of both the magnetically induced current density (MICD) and induced magnetic field (Bind) allows us to classify this cluster as doubly σ- and also π-aromatic on the magnetic criterion. These findings contradict the classical Re–Re double bond representation and favor a chemical bonding pattern that involves delocalized bonds. | |
| dc.description.sponsorship | Consejo Nacional de Ciencia, Tecnología e Innovación Tecnológica - Concytec | |
| dc.identifier.doi | https://doi.org/10.1021/acs.jpclett.5b01816 | |
| dc.identifier.isi | 364435800007 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12390/1115 | |
| dc.language.iso | eng | |
| dc.publisher | American Chemical Society | |
| dc.relation.ispartof | Journal of Physical Chemistry Letters | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.subject | Química física | |
| dc.subject | Física | es_PE |
| dc.subject.ocde | https://purl.org/pe-repo/ocde/ford#1.04.03 | |
| dc.title | New Insights into Re-3(mu-Cl)(3)Cl-6 Aromaticity. Evidence of sigma- and pi-Diatropicity | |
| dc.type | info:eu-repo/semantics/article | |
| dspace.entity.type | Publication |