Publicación:
Molecular dynamics of carboxymethyl ?/?-hybrid carrageenan films doped with NH4I

dc.contributor.author Torres F.G. es_PE
dc.contributor.author Arroyo J. es_PE
dc.contributor.author Alvarez R. es_PE
dc.contributor.author Rodriguez S. es_PE
dc.contributor.author Troncoso O. es_PE
dc.contributor.author López D. es_PE
dc.date.accessioned 2024-05-30T23:13:38Z
dc.date.available 2024-05-30T23:13:38Z
dc.date.issued 2019
dc.description This work was supported by the Vice-Rectorate for Research of the Pontificia Universidad Católica del Perú, the National Council of Science, Technology and Technological Innovation of Peru (CONCYTEC/FONDECYT) and The National Innovation Program for Competitiveness and Productivity (INNOVATE-PERU) of the Peruvian Ministry of Production.
dc.description.abstract The effect of carboxymethylation and NH4I incorporation on the molecular dynamics of carrageenan films was studied. Broadband Dielectric Spectroscopy (BDS) assessed the presence of ? and ? relaxation processes. The effect of NH4I content was analyzed using the Havriliak-Negami model and parameterizing the temperature dependence of the relaxation times according to the Vogel-Fulcher-Tammann-Hesse (VFTH) equation. The glass transition temperature was found to decrease with the increase of NH4I content. These results suggest that carboxymethylation and the salt doping treatment increase the molecular mobility of NH4+ ions, making the films suitable for the development of solid electrolytes for energy storage applications. © 2018, © 2018 Taylor & Francis Group, LLC.
dc.description.sponsorship Consejo Nacional de Ciencia, Tecnología e Innovación Tecnológica - Concytec
dc.identifier.doi https://doi.org/10.1080/03602559.2018.1542713
dc.identifier.scopus 2-s2.0-85075032235
dc.identifier.uri https://hdl.handle.net/20.500.12390/2300
dc.language.iso eng
dc.publisher Taylor and Francis Inc.
dc.relation.ispartof Polymer-Plastics Technology and Materials
dc.rights info:eu-repo/semantics/openAccess
dc.subject solid electrolytes
dc.subject ammonium iodide doping es_PE
dc.subject carboxymethylation es_PE
dc.subject Carrageenan es_PE
dc.subject.ocde http://purl.org/pe-repo/ocde/ford#1.05.10
dc.title Molecular dynamics of carboxymethyl ?/?-hybrid carrageenan films doped with NH4I
dc.type info:eu-repo/semantics/article
dspace.entity.type Publication
Archivos